Aerodyne Research, Inc.
Real-Time CO2 Isotopic Analyzer
 

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A Novel Dual Cell gas analysis system for continuous, accurate, simultaneous measurement of concentrations of Carbon Dioxide isotopologues.

A room temperature QCL laser from Alpes Lasers, is operated in the 2310 to 2315 cm-1 range to
 obtain simultaneous detection of 13CO2 and C18OO and  12CO2

APPLICATIONS:

  • Atmospheric monitoring of isotopic gradients from aircraft and other mobile platforms

  • Eddy covariance iso-flux measurements

  • Isotopic composition measurements

ADVANTAGES:

  • Both 13C and 18O Isotopic Ratios are monitored in real-time

  • Single TE cooled Quantum Cascade Laser (QCL)       

  •  2 matched absorption cells, 7 m.

  • No pre-concentration is required

  • Measurement precision:

0.2δ  in one second, or

0.03δ in 300 sec.

  • Fast time response:  (1/e) response time of 0.05 sec in the 0.3 liter sampling cell

  • Compact 19 inch rack mountable system

 

Click here for a Typical isotopologue-specific spectral scan in the 2310 cm-1 region, taken from the TDLWintel data acquisition screen, using the dual-cell QCL spectrometer. 

ADVANTAGES of Novel Dual Cell Approach (sample + reference)

(1) optical simplicity and higher optical power
(2) negligible spectral interference between the two isotopic species. 

  • The two multi-pass cells are thermally coupled.

  • Cell temperatures measured to a relative precision of 1 mK to minimize compensation for the temperature sensitivity.

  • Temperature control of entire optical bench and electronics minimizes drifts in laser line width, frequency, tuning rate and power variation.

TECHNICAL SPECIFICATIONS:

 Technical specifications for the CO2 Isotope Analyzer with both LN2-cooled detectors and TE-cooled detectors are given below: 

 

δ 13CO2

δ C18OO

Laser Frequency

2310 cm-1

2310 cm-1

RMS noise in ratio

for 1 second data1

0.2 ‰ LN2

(0.6 ‰ TE)

0.2 ‰ LN2

(0.6 ‰ TE)

Intermediate term precision 100 s from Allan plot

0.05 ‰ LN2

(0.1 ‰ TE)

<3%  (linearity)

(0.1 ‰ TE)

Accuracy relative to calibration standard 2

0.1 ‰

0.1 ‰

Sampling frequency3

1 Hz to 20 Hz

Flow cell 1/e time response3

0.05 seconds

1.  The RMS noise definition is defined by the 1 sigma standard deviation of a data stream with a 1 Hz sampling frequency for the ratio of the minor isotope to the major isotope.  The values given are for simultaneous detection of all three isoptopologues.

2.  The absolute concentrations are based on the periodic addition of calibration gases using automated solenoid valve (included).

3.  The sampling frequency of 1 to 20 Hz is the electronic processing speed.  The gas exchange time constant (1/e) in the 0.3 liter volume sampling cell is tau=0.05 seconds with a 420 liter-per-minute vacuum  pump (optional). 

REFERENCES:

"New Method for Isotopic Ratio Measurements of Atmospheric Carbon Dioxide Using a 4.3  micron Pulsed Quantum Cascade Laser," Nelson, D. D.; McManus, J. B.; Herndon, S. C.; Zahniser, M. S.; Tuzson, B.; Emmenegger, L.  Submitted to Applied Physics B.

"Infrared laser spectrometer with balanced absorption for measurements of isotopic ratios of carbon gases," McManus, J.B.; Zahniser, M. S.; Nelson, D. D.; Williams, L. R.; Kolb, C. E.,  Spectrochim. Acta A, 58, 2465-2479, (2002).

"A high precision pulsed QCL spectrometer for measurements of stable isotopes of carbon dioxide," McManus, J. B.; Nelson, D. D.; Shorter, J. H.; Jiménez, R.; Herndon, S.; Saleska, S.; Zahniser, M. S., J. Modern Optics, 52, 2309-2321 (2005).

"What are the instrumentation requirements for measuring the isotopic composition of net ecosystem exchange of CO2 using eddy covariance methods?" Saleska, S. R.; Shorter, J.; Herndon, S.; Jimenéz, R.; McManus, B.; Nelson, D.; Zahniser M.,  Isotopes in Environmental and Health Studies, 42 (1), 117 (2006).

For more information about this product or associated R&D service contact:  

Dr. Mark Zahniser
Vice President
Director, Center for Atmospheric and Environmental Chemistry

Phone: 978-663-9500, Ext. 224
Fax: 978-663-4918
E-mail: mz@aerodyne.com

 

Mr. James Akimchuk, Manager of Adminstration

Phone: 978-663-9500, Ext. 214
Fax: 978-663-4918
E-mail: jima@aerodyne.com

 
 

Aerodyne Research, Inc.  45 Manning Road Billerica, MA  01821-3976  978 663-9500